Low-Loss Anisotropic Image Polaritons in van der Waals Crystal α-MoO3

Sergey G. Menabde, Junghoon Jahng, Sergejs Boroviks, Jongtae Ahn, Jacob T. Heiden, Do Kyung Hwang, Eun Sung Lee, N. Asger Mortensen, Min Seok Jang*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

Orthorhombic molybdenum trioxide (α-MoO3), a newly discovered polaritonic van der Waals crystal, is attracting significant attention due to its strongly anisotropic mid-infrared phonon-polaritons. At the same time, coupling of polariton with its mirror image in an adjacent metal gives rise to a significantly more confined image mode. Here, monocrystalline gold flakes—an atomically flat low-loss substrate for mid-infrared image polaritons—are employed to measure the full complex-valued propagation constant of the hyperbolic image phonon-polaritons in α-MoO3 by near-field probing. The anisotropic dispersion is mapped and the damping of the polaritons propagating at different angles to the crystallographic directions of α-MoO3 is analyzed. These experiments demonstrate the strongly confined image phonon-polaritons in α-MoO3 exhibiting intrinsic limiting lifetime of 4.2 ps and a propagation length of 4.5 times the polariton wavelength, owing to the negligible substrate-mediated loss. Furthermore, it is shown that the image modes with positive group velocity have simultaneously larger momentum and lifetime compared to their counterparts on a dielectric substrate, while the image modes with negative group velocity possess a smaller momentum. These results spotlight the hyperbolic image phonon-polaritons as a superior platform for unconventional light manipulation at the nanoscale.

Original languageEnglish
JournalAdvanced Optical Materials
ISSN2195-1071
DOIs
Publication statusE-pub ahead of print - 6. Sep 2022

Bibliographical note

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

Keywords

  • image polaritons
  • phonon-polaritons
  • van der Waals crystals

Fingerprint

Dive into the research topics of 'Low-Loss Anisotropic Image Polaritons in van der Waals Crystal α-MoO3'. Together they form a unique fingerprint.

Cite this