Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene

Mathias S. Neumann, Amanda F. Smith, Sofie K. Jensen, Rikke Frederiksen, Mathias L. Skavenborg, Jan O. Jeppesen*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

Abstract

The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved 1H NMR spectroscopy.

Original languageEnglish
JournalChemical Communications
Volume59
Issue number42
Pages (from-to)6335-6338
ISSN1359-7345
DOIs
Publication statusPublished - 23. May 2023

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