Electrochemical, spectroelectrochemical, and electrocatalytic properties of novel soluble phthalocyanines containing peripheral thymoxy and chloride units

Rovshen Atajanov; Berfin Huraibat; Zafer Odabaş; Ali Rıza Özkaya

doi:10.1016/j.ica.2022.121360

Electrochemical, spectroelectrochemical, and electrocatalytic properties of novel soluble phthalocyanines containing peripheral thymoxy and chloride units

Rovshen Atajanov, Berfin Huraibat, Zafer Odabaş^*, Ali Rıza Özkaya

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

Novel CoPc, CuPc, Fe(OAc)Pc and Mn(Cl)Pc were synthesized by using original 4-chloro-5-(2-isopropyl-5-methylphenoxy)phthalonitrile in order to investigate their potential redox applications suitable with their chemical and physical characteristics. The molecular structures of new compounds were determined with spectroscopic methods such as elemental analysis, FT-IR, UV–vis, NMR and MALDI TOF MS. Redox behaviours of Fe(OAc)Pc and Mn(Cl)Pc complexes have been probed by using diverse voltammetric techniques such as cyclic (CV) and square wave voltammetry (SWV). In addition, the colour alterations accompanying spectral changes were perused concurrently with electrocolorimetric measurements, and electrocatalytic efficiencies of the all compounds were perused in oxygen reduction reaction.

Original language	English
Article number	121360
Journal	Inorganica Chimica Acta
Volume	547
Number of pages	10
ISSN	0020-1693
DOIs	https://doi.org/10.1016/j.ica.2022.121360
Publication status	Published - 1. Mar 2023

Bibliographical note

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

Electrocatalitic activity
Electrochemistry
Phthalocyanines
Synthesis
Thymoxy
İn-situ Spectroelectrochemistry

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10.1016/j.ica.2022.121360

Cite this

@article{ad485318ec1f474a87c9cb2a5a37aff4,

title = "Electrochemical, spectroelectrochemical, and electrocatalytic properties of novel soluble phthalocyanines containing peripheral thymoxy and chloride units",

abstract = "Novel CoPc, CuPc, Fe(OAc)Pc and Mn(Cl)Pc were synthesized by using original 4-chloro-5-(2-isopropyl-5-methylphenoxy)phthalonitrile in order to investigate their potential redox applications suitable with their chemical and physical characteristics. The molecular structures of new compounds were determined with spectroscopic methods such as elemental analysis, FT-IR, UV–vis, NMR and MALDI TOF MS. Redox behaviours of Fe(OAc)Pc and Mn(Cl)Pc complexes have been probed by using diverse voltammetric techniques such as cyclic (CV) and square wave voltammetry (SWV). In addition, the colour alterations accompanying spectral changes were perused concurrently with electrocolorimetric measurements, and electrocatalytic efficiencies of the all compounds were perused in oxygen reduction reaction.",

keywords = "Electrocatalitic activity, Electrochemistry, Phthalocyanines, Synthesis, Thymoxy, İn-situ Spectroelectrochemistry",

author = "Rovshen Atajanov and Berfin Huraibat and Zafer Odaba{\c s} and {\"O}zkaya, {Ali Rıza}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

month = mar,

day = "1",

doi = "10.1016/j.ica.2022.121360",

language = "English",

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TY - JOUR

T1 - Electrochemical, spectroelectrochemical, and electrocatalytic properties of novel soluble phthalocyanines containing peripheral thymoxy and chloride units

AU - Atajanov, Rovshen

AU - Huraibat, Berfin

AU - Odabaş, Zafer

AU - Özkaya, Ali Rıza

PY - 2023/3/1

Y1 - 2023/3/1

N2 - Novel CoPc, CuPc, Fe(OAc)Pc and Mn(Cl)Pc were synthesized by using original 4-chloro-5-(2-isopropyl-5-methylphenoxy)phthalonitrile in order to investigate their potential redox applications suitable with their chemical and physical characteristics. The molecular structures of new compounds were determined with spectroscopic methods such as elemental analysis, FT-IR, UV–vis, NMR and MALDI TOF MS. Redox behaviours of Fe(OAc)Pc and Mn(Cl)Pc complexes have been probed by using diverse voltammetric techniques such as cyclic (CV) and square wave voltammetry (SWV). In addition, the colour alterations accompanying spectral changes were perused concurrently with electrocolorimetric measurements, and electrocatalytic efficiencies of the all compounds were perused in oxygen reduction reaction.

AB - Novel CoPc, CuPc, Fe(OAc)Pc and Mn(Cl)Pc were synthesized by using original 4-chloro-5-(2-isopropyl-5-methylphenoxy)phthalonitrile in order to investigate their potential redox applications suitable with their chemical and physical characteristics. The molecular structures of new compounds were determined with spectroscopic methods such as elemental analysis, FT-IR, UV–vis, NMR and MALDI TOF MS. Redox behaviours of Fe(OAc)Pc and Mn(Cl)Pc complexes have been probed by using diverse voltammetric techniques such as cyclic (CV) and square wave voltammetry (SWV). In addition, the colour alterations accompanying spectral changes were perused concurrently with electrocolorimetric measurements, and electrocatalytic efficiencies of the all compounds were perused in oxygen reduction reaction.

KW - Electrocatalitic activity

KW - Electrochemistry

KW - Phthalocyanines

KW - Synthesis

KW - Thymoxy

KW - İn-situ Spectroelectrochemistry

U2 - 10.1016/j.ica.2022.121360

DO - 10.1016/j.ica.2022.121360

M3 - Journal article

AN - SCOPUS:85144929439

SN - 0020-1693

VL - 547

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

M1 - 121360

ER -

Electrochemical, spectroelectrochemical, and electrocatalytic properties of novel soluble phthalocyanines containing peripheral thymoxy and chloride units

Abstract

Bibliographical note

Keywords

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Cite this