(E)-6,6'-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate

A superconjugated ligand

Muhib Ahmed, Michael Devereux, Vickie McKee, Malachy McCann, A. Denise Rooney*

*Corresponding author for this work

Research output: Contribution to journalJournal articleResearchpeer-review

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Abstract

Phenanthroline ligands are important metal-binding molecules which have been extensively researched for applications in both material science and medicinal chemistry. Azobenzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as molecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2∙2CHCl3.

Original languageEnglish
JournalActa Crystallographica Section E: Crystallographic Communications
Volume75
Issue numberPart 8
Pages (from-to)1224-1227
Number of pages4
ISSN2056-9890
DOIs
Publication statusPublished - Aug 2019

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Chloroform
Ligands
Optical data storage
Logic devices
ligands
Phenanthrolines
Azobenzene
Materials science
materials science
logic
Crystal structure
Metals
chemistry
Derivatives
Data storage equipment
crystal structure
Molecules
metals
molecules
diazene

Keywords

  • Crystal structure
  • Diazo
  • Phenanthroline
  • Superconjugated ligand

Cite this

@article{e885cd738f0d4c3aacb7dc7759d1c904,
title = "(E)-6,6'-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate: A superconjugated ligand",
abstract = "Phenanthroline ligands are important metal-binding molecules which have been extensively researched for applications in both material science and medicinal chemistry. Azobenzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as molecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2∙2CHCl3.",
keywords = "Crystal structure, Diazo, Phenanthroline, Superconjugated ligand",
author = "Muhib Ahmed and Michael Devereux and Vickie McKee and Malachy McCann and {Denise Rooney}, A.",
year = "2019",
month = "8",
doi = "10.1107/S205698901900954X",
language = "English",
volume = "75",
pages = "1224--1227",
journal = "Acta Crystallographica. Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "Wiley-Blackwell",
number = "Part 8",

}

(E)-6,6'-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate : A superconjugated ligand. / Ahmed, Muhib; Devereux, Michael; McKee, Vickie; McCann, Malachy; Denise Rooney, A.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 75, No. Part 8, 08.2019, p. 1224-1227.

Research output: Contribution to journalJournal articleResearchpeer-review

TY - JOUR

T1 - (E)-6,6'-(Diazene-1,2-diyl)bis(1,10-phenanthrolin-5-ol) trichloromethane disolvate

T2 - A superconjugated ligand

AU - Ahmed, Muhib

AU - Devereux, Michael

AU - McKee, Vickie

AU - McCann, Malachy

AU - Denise Rooney, A.

PY - 2019/8

Y1 - 2019/8

N2 - Phenanthroline ligands are important metal-binding molecules which have been extensively researched for applications in both material science and medicinal chemistry. Azobenzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as molecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2∙2CHCl3.

AB - Phenanthroline ligands are important metal-binding molecules which have been extensively researched for applications in both material science and medicinal chemistry. Azobenzene and its derivatives have received significant attention because of their ability to be reversibly switched between the E and Z forms and so could have applications in optical memory and logic devices or as molecular machines. Herein we report the formation and crystal structure of a highly unusual novel diazo-diphenanthroline compound, C24H14N6O2∙2CHCl3.

KW - Crystal structure

KW - Diazo

KW - Phenanthroline

KW - Superconjugated ligand

U2 - 10.1107/S205698901900954X

DO - 10.1107/S205698901900954X

M3 - Journal article

VL - 75

SP - 1224

EP - 1227

JO - Acta Crystallographica. Section E: Structure Reports Online

JF - Acta Crystallographica. Section E: Structure Reports Online

SN - 1600-5368

IS - Part 8

ER -