Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David Poulsen de Sousa; Jennifer O. Bigelow; Jonas Sundberg; Lawrence Que Jr.; Christine Joy McKenzie

doi:10.1039/C4CC08785B

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

David Poulsen de Sousa, Jennifer O. Bigelow, Jonas Sundberg, Lawrence Que Jr., Christine Joy McKenzie

Department of Physics, Chemistry and Pharmacy

Research output: Contribution to journal › Journal article › Research › peer-review

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Abstract

A Cr(iv)η ²-peroxo complex crystallizes from 33% aqueous H ₂O ₂. The complex is a likely intermediate in catalytic disproportionation of H ₂O ₂ proposed to occur through a single metal site mechanism in solution-and solid state.

Original language	English
Journal	Chemical Communications
Volume	51
Issue number	14
Pages (from-to)	2802-2805
ISSN	1359-7345
DOIs	https://doi.org/10.1039/C4CC08785B
Publication status	Published - 2015

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10.1039/C4CC08785B

c4cc08785bFinal published version, 1.89 MBLicence: CC BY

1 Ph.D. thesis

New Catalysts for Oxidation Reactions
Poulsen de Sousa, D., Apr 2017, Odense: Syddansk Universitet. Det Naturvidenskabelige Fakultet. 291 p.
Research output: Thesis › Ph.D. thesis

Cite this

@article{13f51c839fc64f9db754c1ac6f044605,

title = "Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)",

abstract = "A Cr(iv)η 2-peroxo complex crystallizes from 33% aqueous H 2O 2. The complex is a likely intermediate in catalytic disproportionation of H 2O 2 proposed to occur through a single metal site mechanism in solution-and solid state.",

author = "{Poulsen de Sousa}, David and {O. Bigelow}, Jennifer and Jonas Sundberg and {Que Jr.}, Lawrence and McKenzie, {Christine Joy}",

year = "2015",

doi = "10.1039/C4CC08785B",

language = "English",

volume = "51",

pages = "2802--2805",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "14",

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T1 - Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

AU - Poulsen de Sousa, David

AU - O. Bigelow, Jennifer

AU - Sundberg, Jonas

AU - Que Jr., Lawrence

AU - McKenzie, Christine Joy

PY - 2015

Y1 - 2015

N2 - A Cr(iv)η 2-peroxo complex crystallizes from 33% aqueous H 2O 2. The complex is a likely intermediate in catalytic disproportionation of H 2O 2 proposed to occur through a single metal site mechanism in solution-and solid state.

AB - A Cr(iv)η 2-peroxo complex crystallizes from 33% aqueous H 2O 2. The complex is a likely intermediate in catalytic disproportionation of H 2O 2 proposed to occur through a single metal site mechanism in solution-and solid state.

U2 - 10.1039/C4CC08785B

DO - 10.1039/C4CC08785B

M3 - Journal article

SN - 1359-7345

VL - 51

SP - 2802

EP - 2805

JO - Chemical Communications

JF - Chemical Communications

IS - 14

ER -

Caught! Crystal trapping of a side-on peroxo bound to Cr(IV)

Abstract

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Related research output

New Catalysts for Oxidation Reactions

Cite this