A High Throughput Platform to Minimize Voltage and Fill Factor Losses

Organic photovoltaics (OPV) now can exceed 20% power conversion efficiency in single junction solar cells. To close the remaining gap to competing technologies, both fill factor and open-circuit voltage must be optimized. The Langevin reduction factor is a well-known concept that measures the degree to which charge extraction is favored over charge recombination. It is therefore ideally suited as an optimization target in high-throughput workflows; however, its evaluation so far requires expert interaction. Here, an integrated high-throughput workflow is presented, able to obtain the Langevin reduction factor within a few seconds with high accuracy without human intervention and thus suited for autonomous experiments. This is achieved by combining evidence from UV–vis spectra, current–voltage curves, and a novel implementation of microsecond transient absorption kinetics allowing, for the first time, the intrinsic determination of charge absorption cross-sections, which is crucial to reporting stationary charge densities. The method is demonstrated by varying the donor:acceptor ratio of the high performance OPV blend PM6:Y12. The high reproducibility of the method allows to find a strictly exponential relationship between the PM6 exciton energy and the Langevin reduction factor.