π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

N. L. Bill; J. M. Lim; C. M. Davis; S. Bähring; J. O. Jeppesen; D. Kim; J. L. Sessler

doi:10.1039/c4cc02567a

π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

N. L. Bill
, J. M. Lim
, C. M. Davis
, S. Bähring
, J. O. Jeppesen
, D. Kim
, J. L. Sessler

Department of Physics, Chemistry and Pharmacy

Research output: Contribution to journal › Journal article › Research › peer-review

Abstract

A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

Original language	English
Journal	Chemical Communications
Volume	50
Issue number	51
Pages (from-to)	6758-6761
ISSN	1359-7345
DOIs	https://doi.org/10.1039/c4cc02567a
Publication status	Published - 2014

Keywords

Boron Compounds/chemistry
Electrochemistry
Electromagnetic Fields
Fluorescence
Oxidants/chemistry
Oxidation-Reduction
Spectroscopy, Near-Infrared

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10.1039/c4cc02567a

http://www.scopus.com/inward/record.url?eid=2-s2.0-84901755282&partnerID=40&md5=4061a92a07694c149e38171638e911f5

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Cite this

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abstract = "A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched {"}on-off-on{"} emissive system. This journal is",

keywords = "Boron Compounds/chemistry, Electrochemistry, Electromagnetic Fields, Fluorescence, Oxidants/chemistry, Oxidation-Reduction, Spectroscopy, Near-Infrared",

author = "Bill, \{N. L.\} and Lim, \{J. M.\} and Davis, \{C. M.\} and S. B{\"a}hring and Jeppesen, \{J. O.\} and D. Kim and Sessler, \{J. L.\}",

note = "Cited By :2 Export Date: 30 March 2015",

year = "2014",

doi = "10.1039/c4cc02567a",

language = "English",

volume = "50",

pages = "6758--6761",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

AU - Bill, N. L.

AU - Lim, J. M.

AU - Davis, C. M.

AU - Bähring, S.

AU - Jeppesen, J. O.

AU - Kim, D.

AU - Sessler, J. L.

N1 - Cited By :2 Export Date: 30 March 2015

PY - 2014

Y1 - 2014

N2 - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

AB - A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

KW - Boron Compounds/chemistry

KW - Electrochemistry

KW - Electromagnetic Fields

KW - Fluorescence

KW - Oxidants/chemistry

KW - Oxidation-Reduction

KW - Spectroscopy, Near-Infrared

U2 - 10.1039/c4cc02567a

DO - 10.1039/c4cc02567a

M3 - Journal article

C2 - 24831301

SN - 1359-7345

VL - 50

SP - 6758

EP - 6761

JO - Chemical Communications

JF - Chemical Communications

IS - 51

ER -

π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

Abstract

Keywords

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