Use of solvent to regulate the degree of polymerisation in weakly associated supramolecular oligomers

Steffen Bähring, D. S. Kim, T. Duedal, V. M. Lynch, K. A. Nielsen, J. O. Jeppesen, J. L. Sessler

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Abstrakt

Using a tetrathiafulvalene functionalised calix[4] pyrrole (TTF-C[4]P; 1) and alkyl diester-linked bis-dinitrophenols (2-4), it was found that the solvent polarity and linker length have an effect on the molecular aggregation behaviour. 2D H-1 NOESY, DOSY NMR and UV-vis-NIR spectroscopic studies, as well as single crystal X-ray diffraction analyses support these conclusions.
OriginalsprogEngelsk
TidsskriftChemical Communications
Vol/bind50
Udgave nummer41
Sider (fra-til)5497-5499
ISSN1359-7345
DOI
StatusUdgivet - 2014

Bibliografisk note

ISI Document Delivery No.: AG3QE Times Cited: 2 Cited Reference Count: 10 Bahring, Steffen Kim, Dong Sub Duedal, Troels Lynch, Vincent M. Nielsen, Kent A. Jeppesen, Jan O. Sessler, Jonathan L. National Science Foundation [CHE-1057904]; Robert A. Welch Foundation [F-1018]; Villum Foundation; Danish Natural Science Research Council (FNU) [11-106744] This work was supported by the National Science Foundation (grant CHE-1057904 to J.L.S.), the Robert A. Welch Foundation (grant F-1018 to J.L.S.), the Villum Foundation (to J.O.J.), and the Danish Natural Science Research Council (FNU, Project 11-106744 to J.O.J.). 2 ROYAL SOC CHEMISTRY CAMBRIDGE CHEM COMMUN

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