Synthesis and structural studies of quinolone-based Zn(II), Mn(II) and Ca(II) complexes involving supramolecular interactions

Valentina Stefanou; Dimitris Matiadis; Dimitrios Tsironis; Olga Igglessi-Markopoulou; Vickie Mckee; John Markopoulos

doi:10.1080/00958972.2022.2139611

Synthesis and structural studies of quinolone-based Zn(II), Mn(II) and Ca(II) complexes involving supramolecular interactions

Valentina Stefanou, Dimitris Matiadis^*, Dimitrios Tsironis, Olga Igglessi-Markopoulou, Vickie Mckee, John Markopoulos

^*Kontaktforfatter

Institut for Fysik, Kemi og Farmaci

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

In the present work, we report a detailed investigation of four supramolecular coordination complexes, Zn(Quino)₂(CH₃OH)₂ 2, Zn(Quino)₂H₂O 3, Mn(Quino)₂(CH₃OH)₂ 4 and Ca(Quino)₂(CH₃OH)₂ 5, obtained from the self-assembling of Zn(II), Mn(II) and Ca(II) acceptors with the N-phenyl-4-hydroxyquinoline ligand donor QuinoH 1, possessing the β,β′-diketonate moiety. The structure of the supramolecular arrangement of the isolated complexes have been investigated by single crystal X-ray crystallography. The synthetic N-phenyl quinolone-linker that forms a π–π stacking supramolecular synthon with the coordination preferences of metal ions has been used to construct coordination driven self-assembled “metallosupramolecular” architectures. (Figure presented.).

Originalsprog	Engelsk
Tidsskrift	Journal of Coordination Chemistry
Vol/bind	75
Udgave nummer	19-24
Sider (fra-til)	2661-2676
ISSN	0095-8972
DOI	https://doi.org/10.1080/00958972.2022.2139611
Status	Udgivet - 2022

Bibliografisk note

Publisher Copyright:
© 2022 Informa UK Limited, trading as Taylor & Francis Group.

Dokumenter og links

10.1080/00958972.2022.2139611

SDU link

Tjek adgangen til materialet i Syddansk Universitetsbiblioteks søgemaskine

Citationsformater

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title = "Synthesis and structural studies of quinolone-based Zn(II), Mn(II) and Ca(II) complexes involving supramolecular interactions",

abstract = "In the present work, we report a detailed investigation of four supramolecular coordination complexes, Zn(Quino)2(CH3OH)2 2, Zn(Quino)2H2O 3, Mn(Quino)2(CH3OH)2 4 and Ca(Quino)2(CH3OH)2 5, obtained from the self-assembling of Zn(II), Mn(II) and Ca(II) acceptors with the N-phenyl-4-hydroxyquinoline ligand donor QuinoH 1, possessing the β,β′-diketonate moiety. The structure of the supramolecular arrangement of the isolated complexes have been investigated by single crystal X-ray crystallography. The synthetic N-phenyl quinolone-linker that forms a π–π stacking supramolecular synthon with the coordination preferences of metal ions has been used to construct coordination driven self-assembled “metallosupramolecular” architectures. (Figure presented.).",

keywords = "Ca(II) complex, Mn(II) complex, Quinolones, X-ray crystal structure, Zn(II) complex",

author = "Valentina Stefanou and Dimitris Matiadis and Dimitrios Tsironis and Olga Igglessi-Markopoulou and Vickie Mckee and John Markopoulos",

note = "Publisher Copyright: {\textcopyright} 2022 Informa UK Limited, trading as Taylor & Francis Group.",

year = "2022",

doi = "10.1080/00958972.2022.2139611",

language = "English",

volume = "75",

pages = "2661--2676",

journal = "Journal of Coordination Chemistry",

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TY - JOUR

T1 - Synthesis and structural studies of quinolone-based Zn(II), Mn(II) and Ca(II) complexes involving supramolecular interactions

AU - Stefanou, Valentina

AU - Matiadis, Dimitris

AU - Tsironis, Dimitrios

AU - Igglessi-Markopoulou, Olga

AU - Mckee, Vickie

AU - Markopoulos, John

PY - 2022

Y1 - 2022

N2 - In the present work, we report a detailed investigation of four supramolecular coordination complexes, Zn(Quino)2(CH3OH)2 2, Zn(Quino)2H2O 3, Mn(Quino)2(CH3OH)2 4 and Ca(Quino)2(CH3OH)2 5, obtained from the self-assembling of Zn(II), Mn(II) and Ca(II) acceptors with the N-phenyl-4-hydroxyquinoline ligand donor QuinoH 1, possessing the β,β′-diketonate moiety. The structure of the supramolecular arrangement of the isolated complexes have been investigated by single crystal X-ray crystallography. The synthetic N-phenyl quinolone-linker that forms a π–π stacking supramolecular synthon with the coordination preferences of metal ions has been used to construct coordination driven self-assembled “metallosupramolecular” architectures. (Figure presented.).

AB - In the present work, we report a detailed investigation of four supramolecular coordination complexes, Zn(Quino)2(CH3OH)2 2, Zn(Quino)2H2O 3, Mn(Quino)2(CH3OH)2 4 and Ca(Quino)2(CH3OH)2 5, obtained from the self-assembling of Zn(II), Mn(II) and Ca(II) acceptors with the N-phenyl-4-hydroxyquinoline ligand donor QuinoH 1, possessing the β,β′-diketonate moiety. The structure of the supramolecular arrangement of the isolated complexes have been investigated by single crystal X-ray crystallography. The synthetic N-phenyl quinolone-linker that forms a π–π stacking supramolecular synthon with the coordination preferences of metal ions has been used to construct coordination driven self-assembled “metallosupramolecular” architectures. (Figure presented.).

KW - Ca(II) complex

KW - Mn(II) complex

KW - Quinolones

KW - X-ray crystal structure

KW - Zn(II) complex

U2 - 10.1080/00958972.2022.2139611

DO - 10.1080/00958972.2022.2139611

M3 - Journal article

AN - SCOPUS:85141425566

SN - 0095-8972

VL - 75

SP - 2661

EP - 2676

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 19-24

ER -

Synthesis and structural studies of quinolone-based Zn(II), Mn(II) and Ca(II) complexes involving supramolecular interactions

Abstract

Bibliografisk note

Dokumenter og links

SDU link

Fingeraftryk

Citationsformater