Synthesis and Characterization of Layered Double Hydroxides Containing Optically Active Transition Metal Ion

S. B. Tyagi, Aneeta Kharkwal, Nitu, Mamta Kharkwal*, Raghunandan Sharma

*Kontaktforfatter for dette arbejde

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

Resumé

The acetate intercalated layered double hydroxides of Zn and Mn, have been synthesized by chimie douce method. The materials were characterized by XRD, TGA, CHN, IR, XPS, SEM-EDX and UV-visible spectroscopy. The photoluminescence properties was also studied. The optical properties of layered hydroxides are active transition metal ion dependent, particularly d1−10 system plays an important role. Simultaneously the role of host – guest orientation has been considered the basis of photoluminescence. Acetate ion can be exchanged with iodide and sulphate ions. The decomposed product resulted the pure phase Mn doped zinc oxide are also reported.

OriginalsprogEngelsk
TidsskriftSolid State Sciences
Vol/bind63
Sider (fra-til)93-102
ISSN1293-2558
DOI
StatusUdgivet - 2017
Udgivet eksterntJa

Fingeraftryk

Hydroxides
hydroxides
Transition metals
Metal ions
acetates
metal ions
Photoluminescence
Acetates
transition metals
Ions
Zinc Oxide
photoluminescence
Iodides
synthesis
Zinc oxide
zinc oxides
iodides
Sulfates
Energy dispersive spectroscopy
sulfates

Citer dette

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title = "Synthesis and Characterization of Layered Double Hydroxides Containing Optically Active Transition Metal Ion",
abstract = "The acetate intercalated layered double hydroxides of Zn and Mn, have been synthesized by chimie douce method. The materials were characterized by XRD, TGA, CHN, IR, XPS, SEM-EDX and UV-visible spectroscopy. The photoluminescence properties was also studied. The optical properties of layered hydroxides are active transition metal ion dependent, particularly d1−10 system plays an important role. Simultaneously the role of host – guest orientation has been considered the basis of photoluminescence. Acetate ion can be exchanged with iodide and sulphate ions. The decomposed product resulted the pure phase Mn doped zinc oxide are also reported.",
keywords = "Intercalation, Ion exchange, Layered double hydroxides, Photoluminescence",
author = "Tyagi, {S. B.} and Aneeta Kharkwal and Nitu and Mamta Kharkwal and Raghunandan Sharma",
year = "2017",
doi = "10.1016/j.solidstatesciences.2016.11.012",
language = "English",
volume = "63",
pages = "93--102",
journal = "Solid State Sciences",
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Synthesis and Characterization of Layered Double Hydroxides Containing Optically Active Transition Metal Ion. / Tyagi, S. B.; Kharkwal, Aneeta; Nitu; Kharkwal, Mamta; Sharma, Raghunandan.

I: Solid State Sciences, Bind 63, 2017, s. 93-102.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

T1 - Synthesis and Characterization of Layered Double Hydroxides Containing Optically Active Transition Metal Ion

AU - Tyagi, S. B.

AU - Kharkwal, Aneeta

AU - Nitu,

AU - Kharkwal, Mamta

AU - Sharma, Raghunandan

PY - 2017

Y1 - 2017

N2 - The acetate intercalated layered double hydroxides of Zn and Mn, have been synthesized by chimie douce method. The materials were characterized by XRD, TGA, CHN, IR, XPS, SEM-EDX and UV-visible spectroscopy. The photoluminescence properties was also studied. The optical properties of layered hydroxides are active transition metal ion dependent, particularly d1−10 system plays an important role. Simultaneously the role of host – guest orientation has been considered the basis of photoluminescence. Acetate ion can be exchanged with iodide and sulphate ions. The decomposed product resulted the pure phase Mn doped zinc oxide are also reported.

AB - The acetate intercalated layered double hydroxides of Zn and Mn, have been synthesized by chimie douce method. The materials were characterized by XRD, TGA, CHN, IR, XPS, SEM-EDX and UV-visible spectroscopy. The photoluminescence properties was also studied. The optical properties of layered hydroxides are active transition metal ion dependent, particularly d1−10 system plays an important role. Simultaneously the role of host – guest orientation has been considered the basis of photoluminescence. Acetate ion can be exchanged with iodide and sulphate ions. The decomposed product resulted the pure phase Mn doped zinc oxide are also reported.

KW - Intercalation

KW - Ion exchange

KW - Layered double hydroxides

KW - Photoluminescence

U2 - 10.1016/j.solidstatesciences.2016.11.012

DO - 10.1016/j.solidstatesciences.2016.11.012

M3 - Journal article

VL - 63

SP - 93

EP - 102

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

ER -