Photovoltaic Properties and Ultrafast Plasmon Relaxation Dynamics of Diamond-Like Carbon Nanocomposite Films with Embedded Ag Nanoparticles

Sigitas Tamulevičius, Šarūnas Meškinis, Domantas Peckus, Andrius Vasiliauskas, Arvydas Čiegis, Rimantas Gudaitis, Tomas Tamulevičius, Iryna Yaremchuk*

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Resumé

Ultrafast relaxation dynamics of diamond-like carbon (DLC) films with embedded Ag nanoparticles (DLC:Ag) and photovoltaic properties of heterojunctions consisting of DLC:Ag and crystalline silicon (DLC:Ag/Si) were investigated by means of transient absorption (TAS) spectroscopy and photovoltaic measurements. The heterojunctions using both p type and n type silicon were studied. It was found that TAS spectra of DLC:Ag films were dependent on the used excitation wavelength. At wavelengths where Ag nanoparticles absorbed light most intensively, only DLC signal was registered. This result is in good accordance with an increase of the DLC:Ag/Si heterojunction short circuit current and open circuit voltage with the excitation wavelength in the photovoltaic measurements. The dependence of the TAS spectra of DLC:Ag films and photovoltaic properties of DLC:Ag/Si heterostructures on the excitation wavelength was explained as a result of trapping of the photoexcited hot charge carriers in DLC matrix. The negative photovoltaic effect was observed for DLC:Ag/p-Si heterostructures and positive (“conventional”) for DLC:Ag/n-Si ones. It was explained by the excitation of hot plasmonic holes in the Ag nanoparticles embedded into DLC matrix. Some decrease of DLC:Ag/Si heterostructures photovoltage as well as photocurrent with DLC:Ag film thickness was observed, indicating role of the interface in the charge transfer process of photocarriers excited in Ag nanoparticles.

OriginalsprogEngelsk
Artikelnummer288
TidsskriftNanoscale Research Letters
Vol/bind12
Udgave nummer1
Antal sider10
ISSN1931-7573
DOI
StatusUdgivet - 1. dec. 2017

Fingeraftryk

Diamond
Nanocomposite films
Carbon films
Diamonds
nanocomposites
Carbon
diamonds
Nanoparticles
nanoparticles
carbon
Heterojunctions
Wavelength
heterojunctions
Silicon
wavelengths
Absorption spectra
excitation
Photovoltaic effects
Diamond like carbon films
absorption spectra

Citer dette

Tamulevičius, Sigitas ; Meškinis, Šarūnas ; Peckus, Domantas ; Vasiliauskas, Andrius ; Čiegis, Arvydas ; Gudaitis, Rimantas ; Tamulevičius, Tomas ; Yaremchuk, Iryna. / Photovoltaic Properties and Ultrafast Plasmon Relaxation Dynamics of Diamond-Like Carbon Nanocomposite Films with Embedded Ag Nanoparticles. I: Nanoscale Research Letters. 2017 ; Bind 12, Nr. 1.
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title = "Photovoltaic Properties and Ultrafast Plasmon Relaxation Dynamics of Diamond-Like Carbon Nanocomposite Films with Embedded Ag Nanoparticles",
abstract = "Ultrafast relaxation dynamics of diamond-like carbon (DLC) films with embedded Ag nanoparticles (DLC:Ag) and photovoltaic properties of heterojunctions consisting of DLC:Ag and crystalline silicon (DLC:Ag/Si) were investigated by means of transient absorption (TAS) spectroscopy and photovoltaic measurements. The heterojunctions using both p type and n type silicon were studied. It was found that TAS spectra of DLC:Ag films were dependent on the used excitation wavelength. At wavelengths where Ag nanoparticles absorbed light most intensively, only DLC signal was registered. This result is in good accordance with an increase of the DLC:Ag/Si heterojunction short circuit current and open circuit voltage with the excitation wavelength in the photovoltaic measurements. The dependence of the TAS spectra of DLC:Ag films and photovoltaic properties of DLC:Ag/Si heterostructures on the excitation wavelength was explained as a result of trapping of the photoexcited hot charge carriers in DLC matrix. The negative photovoltaic effect was observed for DLC:Ag/p-Si heterostructures and positive (“conventional”) for DLC:Ag/n-Si ones. It was explained by the excitation of hot plasmonic holes in the Ag nanoparticles embedded into DLC matrix. Some decrease of DLC:Ag/Si heterostructures photovoltage as well as photocurrent with DLC:Ag film thickness was observed, indicating role of the interface in the charge transfer process of photocarriers excited in Ag nanoparticles.",
keywords = "Charge transfer, Diamond-like carbon, Electron-phonon interaction, Hot electrons, Localized surface plasmon resonance, Magnetron sputtering, Nanocomposites, Photovoltaic properties, Silver nanoparticles",
author = "Sigitas Tamulevičius and Šarūnas Meškinis and Domantas Peckus and Andrius Vasiliauskas and Arvydas Čiegis and Rimantas Gudaitis and Tomas Tamulevičius and Iryna Yaremchuk",
year = "2017",
month = "12",
day = "1",
doi = "10.1186/s11671-017-2065-1",
language = "English",
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journal = "Nanoscale Research Letters",
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Photovoltaic Properties and Ultrafast Plasmon Relaxation Dynamics of Diamond-Like Carbon Nanocomposite Films with Embedded Ag Nanoparticles. / Tamulevičius, Sigitas; Meškinis, Šarūnas; Peckus, Domantas; Vasiliauskas, Andrius; Čiegis, Arvydas; Gudaitis, Rimantas; Tamulevičius, Tomas; Yaremchuk, Iryna.

I: Nanoscale Research Letters, Bind 12, Nr. 1, 288, 01.12.2017.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

TY - JOUR

T1 - Photovoltaic Properties and Ultrafast Plasmon Relaxation Dynamics of Diamond-Like Carbon Nanocomposite Films with Embedded Ag Nanoparticles

AU - Tamulevičius, Sigitas

AU - Meškinis, Šarūnas

AU - Peckus, Domantas

AU - Vasiliauskas, Andrius

AU - Čiegis, Arvydas

AU - Gudaitis, Rimantas

AU - Tamulevičius, Tomas

AU - Yaremchuk, Iryna

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Ultrafast relaxation dynamics of diamond-like carbon (DLC) films with embedded Ag nanoparticles (DLC:Ag) and photovoltaic properties of heterojunctions consisting of DLC:Ag and crystalline silicon (DLC:Ag/Si) were investigated by means of transient absorption (TAS) spectroscopy and photovoltaic measurements. The heterojunctions using both p type and n type silicon were studied. It was found that TAS spectra of DLC:Ag films were dependent on the used excitation wavelength. At wavelengths where Ag nanoparticles absorbed light most intensively, only DLC signal was registered. This result is in good accordance with an increase of the DLC:Ag/Si heterojunction short circuit current and open circuit voltage with the excitation wavelength in the photovoltaic measurements. The dependence of the TAS spectra of DLC:Ag films and photovoltaic properties of DLC:Ag/Si heterostructures on the excitation wavelength was explained as a result of trapping of the photoexcited hot charge carriers in DLC matrix. The negative photovoltaic effect was observed for DLC:Ag/p-Si heterostructures and positive (“conventional”) for DLC:Ag/n-Si ones. It was explained by the excitation of hot plasmonic holes in the Ag nanoparticles embedded into DLC matrix. Some decrease of DLC:Ag/Si heterostructures photovoltage as well as photocurrent with DLC:Ag film thickness was observed, indicating role of the interface in the charge transfer process of photocarriers excited in Ag nanoparticles.

AB - Ultrafast relaxation dynamics of diamond-like carbon (DLC) films with embedded Ag nanoparticles (DLC:Ag) and photovoltaic properties of heterojunctions consisting of DLC:Ag and crystalline silicon (DLC:Ag/Si) were investigated by means of transient absorption (TAS) spectroscopy and photovoltaic measurements. The heterojunctions using both p type and n type silicon were studied. It was found that TAS spectra of DLC:Ag films were dependent on the used excitation wavelength. At wavelengths where Ag nanoparticles absorbed light most intensively, only DLC signal was registered. This result is in good accordance with an increase of the DLC:Ag/Si heterojunction short circuit current and open circuit voltage with the excitation wavelength in the photovoltaic measurements. The dependence of the TAS spectra of DLC:Ag films and photovoltaic properties of DLC:Ag/Si heterostructures on the excitation wavelength was explained as a result of trapping of the photoexcited hot charge carriers in DLC matrix. The negative photovoltaic effect was observed for DLC:Ag/p-Si heterostructures and positive (“conventional”) for DLC:Ag/n-Si ones. It was explained by the excitation of hot plasmonic holes in the Ag nanoparticles embedded into DLC matrix. Some decrease of DLC:Ag/Si heterostructures photovoltage as well as photocurrent with DLC:Ag film thickness was observed, indicating role of the interface in the charge transfer process of photocarriers excited in Ag nanoparticles.

KW - Charge transfer

KW - Diamond-like carbon

KW - Electron-phonon interaction

KW - Hot electrons

KW - Localized surface plasmon resonance

KW - Magnetron sputtering

KW - Nanocomposites

KW - Photovoltaic properties

KW - Silver nanoparticles

UR - http://www.scopus.com/inward/record.url?scp=85018467899&partnerID=8YFLogxK

U2 - 10.1186/s11671-017-2065-1

DO - 10.1186/s11671-017-2065-1

M3 - Journal article

VL - 12

JO - Nanoscale Research Letters

JF - Nanoscale Research Letters

SN - 1931-7573

IS - 1

M1 - 288

ER -