Heterocyclic π‐Donors, Macrocycles and Cage Molecules

Jan Becher*, Thomas K. Hansen, Tine Jørgensen, Paul Stein

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    Abstrakt

    Reaction of dmit‐salts 2 and bis‐alkylating agents leads to macrocycles annelated to a 1,3‐dithiole‐2‐thione ring. Intermolecular coupling of monomers MC[n,1] leads to TTF‐crowns of type A whereas intramolecular coupling of dimers MC[n,2] gives TTF‐cages of type B. The complex formation of type A and B host molecules with alkali metal ions is discussed.

    OriginalsprogEngelsk
    TidsskriftBulletin des Sociétés Chimiques Belges
    Vol/bind101
    Udgave nummer7
    Sider (fra-til)555-568
    Antal sider14
    ISSN0037-9646
    DOI
    StatusUdgivet - 1. jan. 1992

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