Abstrakt
Reaction of dmit‐salts 2 and bis‐alkylating agents leads to macrocycles annelated to a 1,3‐dithiole‐2‐thione ring. Intermolecular coupling of monomers MC[n,1] leads to TTF‐crowns of type A whereas intramolecular coupling of dimers MC[n,2] gives TTF‐cages of type B. The complex formation of type A and B host molecules with alkali metal ions is discussed.
Originalsprog | Engelsk |
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Tidsskrift | Bulletin des Sociétés Chimiques Belges |
Vol/bind | 101 |
Udgave nummer | 7 |
Sider (fra-til) | 555-568 |
Antal sider | 14 |
ISSN | 0037-9646 |
DOI | |
Status | Udgivet - 1. jan. 1992 |