Evaluation of the Optimal Reaction Conditions for the Methanolysis and Ethanolysis of Castor Oil Catalyzed by Immobilized Enzymes

Thalles Allan Andrade, Ibrahim F. Al-Kabalawi, Massimiliano Errico, Knud Villy Christensen

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Abstract

As an alternative to the use of chemical catalysts, immobilized enzyme Lipozyme 435 was evaluated as catalyst for biodiesel production, comparing its efficiency in the castor oil transesterification with methanol and ethanol. Different reaction conditions were assessed and optimized, including the reaction temperature (35 – 60 °C), alcohol-to-oil molar ratio (from 3:1 to 6:1), amount of catalyst (from 3 to 15 wt% by weight of oil), addition of water (0 – 15 wt%), and use of n-hexane as a solvent (0 – 75 wt%). For the transesterification with methanol, the optimal reaction conditions were 3:1 methanol-to-oil molar ratio, 5 wt% of enzymes, 7.5 wt% of water, 50 wt% n-hexane, at 50 °C. The fatty acid methyl esters content was 96.8 % and 1.0 % FFA. Regarding the reactions with ethanol, 98.0 % fatty acid ethyl ester was obtained and 1.3 % FFA, when the reaction was carried out at 60 °C, 4:1 ethanol-to-oil molar ratio, 5 wt% of enzymes, 40 wt% of n-hexane and no addition of water.
OriginalsprogEngelsk
Publikationsdato14. maj 2018
Antal sider1
StatusUdgivet - 14. maj 2018
BegivenhedEuropean Biomass Conference & Exhibition - København, Danmark
Varighed: 14. maj 201817. maj 2018
Konferencens nummer: 26
http://www.eubce.com/home.html

Konference

KonferenceEuropean Biomass Conference & Exhibition
Nummer26
Land/OmrådeDanmark
ByKøbenhavn
Periode14/05/201817/05/2018
Internetadresse

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