Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene

Mathias S. Neumann; Amanda F. Smith; Sofie K. Jensen; Rikke Frederiksen; Mathias L. Skavenborg; Jan O. Jeppesen

doi:10.1039/d3cc00360d

Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene

Mathias S. Neumann, Amanda F. Smith, Sofie K. Jensen, Rikke Frederiksen, Mathias L. Skavenborg, Jan O. Jeppesen^*

^*Kontaktforfatter

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved ¹H NMR spectroscopy.

Originalsprog	Engelsk
Tidsskrift	Chemical Communications
Vol/bind	59
Udgave nummer	42
Sider (fra-til)	6335-6338
ISSN	1359-7345
DOI	https://doi.org/10.1039/d3cc00360d
Status	Udgivet - 23. maj 2023

Bibliografisk note

Publisher Copyright:
© 2023 The Royal Society of Chemistry.

Dokumenter og links

10.1039/d3cc00360d

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2 Ph.d.-afhandling

Unidirectional Movement in Redoxactive Molecular Machines
Bidragets oversatte titel: Ensrettet bevægelse i redoxaktive molekylære maskinerJensen, S. K., 24. jun. 2024, Syddansk Universitet. Det Naturvidenskabelige Fakultet. 359 s.
Publikation: Afhandling › Ph.d.-afhandling

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Tetrathiafulvalenes in Molecular Machines – New Building Blocks and Controlled Movement
Neumann, M. S., 30. okt. 2023, Syddansk Universitet. Det Naturvidenskabelige Fakultet. 350 s.
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Citationsformater

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abstract = "The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved 1H NMR spectroscopy.",

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AU - Neumann, Mathias S.

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AU - Jensen, Sofie K.

AU - Frederiksen, Rikke

AU - Skavenborg, Mathias L.

AU - Jeppesen, Jan O.

PY - 2023/5/23

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N2 - The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved 1H NMR spectroscopy.

AB - The unique redox properties of monopyrrolotetrathiafulvalene can be used to induce directional movement in interlocked molecules. In this study, the kinetics for the directional movement of cyclobis(paraquat-p-phenylene) across the dioxidised monopyrrolotetrathiafulvalene in a [2]rotaxane is quantified by time-resolved 1H NMR spectroscopy.

U2 - 10.1039/d3cc00360d

DO - 10.1039/d3cc00360d

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AN - SCOPUS:85153085089

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Evaluating the energy landscape of an out-of-equilibrium bistable [2]rotaxane containing monopyrrolotetrathiafulvalene

Abstract

Bibliografisk note

Dokumenter og links

SDU link

Fingeraftryk

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Unidirectional Movement in Redoxactive Molecular Machines

Tetrathiafulvalenes in Molecular Machines – New Building Blocks and Controlled Movement

Citationsformater