Cover Feature: Probing the Electrostatic Barrier of Tetrathiafulvalene Dications using a Tetra‐stable Donor–Acceptor [2]Rotaxane (Chem. Eur. J. 28/2020)

Morten Jensen, Rikke Kristensen, Sissel S. Andersen, Dan Bendixen, Jan O. Jeppesen*

*Kontaktforfatter for dette arbejde

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Abstrakt

Control of directionality is of paramount importance if rectified motion in electroactive molecular machines should be realized. As illustrated in the cover artwork, the tetracationic ring (blue) in a tetraoxidized [2]rotaxane can follow two different tracks; it transpires that it is easier for the ring to follow a track in which it has to move across a monopyrrolotetrathiafulvalene dication (dark green) compared to the track in which it moves across a tetrathiafulvalene dication (light green).
OriginalsprogEngelsk
TidsskriftChemistry - A European Journal
Vol/bind26
Udgave nummer28
Sider (fra-til)6087-6087
ISSN0947-6539
DOI
StatusUdgivet - 15. maj 2020

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