TY - JOUR
T1 - Correction to:Structure–Property Relationships with Functionalized Subphthalocyanines
T2 - Toward Photovoltaic Devices More Stable to Photooxidative Degradation Mediated by Singlet Oxygen(Advanced Functional Materials, (2023), 10.1002/adfm.202310222)
AU - Aryal, Um Kanta
AU - Atajanov, Rovshen
AU - Broløs, Line
AU - El-Sayed, Ahmed Ali
AU - Henke, Petr
AU - Jespersen, Malte Frydenlund
AU - Langhorn, Line M.
AU - Madsen, Morten
AU - Martos, Daniel Garcia
AU - Mikkelsen, Kurt V.
AU - Mogensen, Josefine
AU - Nielsen, Mogens Brøndsted
AU - Ogilby, Peter R.
AU - Rasmussen, Mads Georg
AU - Rindom, Cecilie
AU - Turkovic, Vida
N1 - Publisher Copyright:
© 2024 Wiley-VCH GmbH.
PY - 2024/5/10
Y1 - 2024/5/10
N2 - Erratum NMR spectra of some compounds in the published paper were not properly recorded and interpreted. This misinterpretation has led to a wrong identification of compound 6. As such, the data and associated discussion on compound 6 should therefore not be considered. However, because compound 6 does not contribute to the main thrust of the paper and its conclusions, our principal message is not altered. Corrected NMR spectra of compound 4 are presented in the Supporting Information. While the 1H-resonances are unaltered, the 13C-NMR resonances should be changed to: Compound 4: 13C NMR (126 MHz, CDCl3) δ 152.60, 152.59, 151.85, 150.39, 150.11, 143.84, 132.46, 132.36, 132.33, 131.35, 131.15, 130.83, 130.27, 130.15, 129.16, 128.35, 127.99, 126.09, 125.87, 125.42, 123.49, 122.49, 122.36, 122.33, 118.59, 117.82, 112.05, 93.93, 90.19, 33.96, 31.45 ppm (6 signals missing due to overlap). The synthetic protocol for compound 5 should be changed to the following (not involving Pd(PPh3)4 as catalyst as stated in Scheme 1): Compound 5: A solution of compound 9 (200 mg, 0.3 mmol) in dry DMF (8 mL) was added to Zn(CN)2 (70 mg, 0.6 mmol) in a 10 mL microwave vial. The reaction tube was sealed and the mixture was heated to 105 °C under microwave irradiation with a hold time of 45 min. Water (20 mL) was added to the mixture that was then extracted with CH2Cl2 (3 × 15 mL). The combined organic extracts were dried over MgSO4, and the solvent was removed by rotary evaporation. Flash column chromatography (SiO2, toluene/ethyl acetate 5%) yielded the product as a dark purple solid (112 mg, 65%). Corrected Scheme 1:.
AB - Erratum NMR spectra of some compounds in the published paper were not properly recorded and interpreted. This misinterpretation has led to a wrong identification of compound 6. As such, the data and associated discussion on compound 6 should therefore not be considered. However, because compound 6 does not contribute to the main thrust of the paper and its conclusions, our principal message is not altered. Corrected NMR spectra of compound 4 are presented in the Supporting Information. While the 1H-resonances are unaltered, the 13C-NMR resonances should be changed to: Compound 4: 13C NMR (126 MHz, CDCl3) δ 152.60, 152.59, 151.85, 150.39, 150.11, 143.84, 132.46, 132.36, 132.33, 131.35, 131.15, 130.83, 130.27, 130.15, 129.16, 128.35, 127.99, 126.09, 125.87, 125.42, 123.49, 122.49, 122.36, 122.33, 118.59, 117.82, 112.05, 93.93, 90.19, 33.96, 31.45 ppm (6 signals missing due to overlap). The synthetic protocol for compound 5 should be changed to the following (not involving Pd(PPh3)4 as catalyst as stated in Scheme 1): Compound 5: A solution of compound 9 (200 mg, 0.3 mmol) in dry DMF (8 mL) was added to Zn(CN)2 (70 mg, 0.6 mmol) in a 10 mL microwave vial. The reaction tube was sealed and the mixture was heated to 105 °C under microwave irradiation with a hold time of 45 min. Water (20 mL) was added to the mixture that was then extracted with CH2Cl2 (3 × 15 mL). The combined organic extracts were dried over MgSO4, and the solvent was removed by rotary evaporation. Flash column chromatography (SiO2, toluene/ethyl acetate 5%) yielded the product as a dark purple solid (112 mg, 65%). Corrected Scheme 1:.
UR - http://www.scopus.com/inward/record.url?scp=85186888871&partnerID=8YFLogxK
U2 - 10.1002/adfm.202400681
DO - 10.1002/adfm.202400681
M3 - Comment/debate
AN - SCOPUS:85186888871
SN - 1616-301X
VL - 34
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 19
M1 - 2400681
ER -