π-Extended tetrathiafulvalene BODIPY (ex-TTF-BODIPY): A redox switched "on-off-on" electrochromic system with two near-infrared fluorescent outputs

N. L. Bill, J. M. Lim, C. M. Davis, S. Bähring, J. O. Jeppesen, D. Kim, J. L. Sessler

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Abstrakt

A π-extended tetrathiafulvalene-boradiazaindacene chimera, ex-TTF-BODIPY, has been prepared. The resulting system undergoes sequential one-electron oxidations, allowing access to both the mono-oxidized radical cationic and dicationic states. Additionally, ex-TTF-BODIPY displays electrochromic and electrofluorochromic behaviour in the near-IR portion of the electromagnetic spectrum and functions as a redox switched "on-off-on" emissive system. This journal is

OriginalsprogEngelsk
TidsskriftChemical Communications
Vol/bind50
Udgave nummer51
Sider (fra-til)6758-6761
ISSN1359-7345
DOI
StatusUdgivet - 2014

Bibliografisk note

Cited By :2 Export Date: 30 March 2015

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